质谱色谱分析检测标准质谱色谱分析-中析研究所检测

(CMA)

(CNAS)

(ISO)

(高新技术企业)

质谱色谱分析相关标准参考信息

GB/T 37185-2018 气体分析室内挥发性有害有机物的测定 “SUMMA罐-硅烷化管”采样气相色谱/质谱联用（GC/MS）法
简介：
信息：ICS：71.040.40 CCS：G86 发布：2018-12-28 00:00:00.0 实施：2019-11-01 00:00:00.0

ASTM C1845-2016 在以电感耦合等离子体质谱法 (ICP-MS)进行的同位素分析中使用高压离子色谱法 (HPIC) 从铀矩阵中分离镧系元素的标准实施规程
简介：5.1x00a0;The measurement of isotopic distributions for the lanthanide series elements is of important to all phases of the nuclear fuels cycle. Examples include the purification of the Nd isotopes from Ce and Sm isotopes for the determination of atom percent fission through the production of 148Nd in irradiated nuclear fuels using Practice C1769, determination of rare earth content and isotopic distribution in Uranium Ore Concentrates (UOC) for source term and production of lanthanide fission products in irradiated nuclear fuels for determination of performance, improvements of depletion codes, and analysis of burnup indicators.3 1.1x00a0;This practice provides instructions for the rapid separation of lanthanide elements using high pressure ion chromatography (HPIC) from dissolved uranium materials such as: nuclear fuels, uranium ores, hydrolyzed UF6, and depleted, natural, or enriched oxides/powders, or metals. When optimized, this technique will produce purified elemental fractions of the lanthanide elements isolated from the bulk uranium matrix allowing for isotopic assay using inductively coupled plasma mass spectrometry (ICP-MS). 1.2x00a0;This practice is most applicable for analyte concentrations of nanograms per gram uranium or higher. For ICP-MS detection and measurement of analyte concentrations lower than this, it would be necessary to perform additional pre-cleanup or concentration techniques, or both, which are not addressed in this practice. 1.3x00a0;When combined with isotope dilution, this practice can also be used for improved precision assays of the lanthanide elements using the principle of isotope dilution mass spectrometry (IDMS). 1.4x00a0;The values stated in SI units are to be regarded as standard. No other units of measurement are included in this practice. 1.5x00a0;This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
信息：ICS： CCS：发布：2016 实施：

BS EN 16143-2013 石油产品.填充油中苯并芘(BaP)和选定的多环芳烃(PAH)的含量测定.使用双液相(LC)清洗和气相色谱-质谱(GC/MS)分析规程
简介：
信息：ICS：75.100 CCS：E30 发布：2013-02-28 实施：2013-02-28

GB/Z 35959-2018 液相色谱-质谱联用分析方法通则
简介：
信息：ICS：71.040.40 CCS：G04 发布：2018-02-06 实施：2018-09-01

GOST 33490-2015 乳和乳制品. 采用气相色谱法和质谱分析检测法检测植物脂肪
简介：
信息：ICS：67.100.10 CCS：X16 发布：2015 实施：2016-07-01

GOST R ISO 16000-14-2013 室内空气. 第14部分. 总体(气体和粒子相)聚氯联二苯(PCB)和多氯代二苯并二恶英/多氯代二苯并呋喃(PCDD/PCDF)的测定. 使用高分辨率气象色谱和质谱分析法进行的提取, 清理和分析
简介：
信息：ICS：13.040.20 CCS：发布：2013 实施：2014-12-01

ASTM D8399-22 使用液相色谱-串联质谱法（LC-MS/MS）对干大麻和大麻原料中农药的多残留分析的标准试验方法
简介：
信息：ICS： CCS：发布：2022-07-01 实施：

GOST 33490-2015 乳和乳制品. 采用气相色谱法和质谱分析检测法检测植物脂肪
简介：
信息：ICS：67.100.10 CCS：发布：2015 实施：2016-07-01

ASTM D6209-2013 环境空气中气态和颗粒多环芳香烃测定的标准试验方法 (用气相色谱/质谱分析的背面吸着剂的滤膜的收集)
简介：5.1x00a0;Polycyclic aromatic hydrocarbons (PAH) as defined by this test method are compounds made up of two or more fused aromatic rings. 5.2x00a0;Several PAH are considered to be probable human carcinogens. 5.3x00a0;PAH are emitted in the atmosphere primarily through wood or fossil fuel combustion. 5.4x00a0;Two- and three-ring PAH are typically present in urban air at concentrations ranging from 10 to several hundred nanograms per cubic metre (ng/m3); those with four or more rings are usually found at concentrations of a few ng/m3 or lower. 5.5x00a0;PAH span a broad spectrum of vapor pressures (for example, from 1.1 x00d7; 10x2013;2 kPa for naphthalene to 2 x00d7; 10x2013;13 kPa for coronene at 25x00b0;C). Table 1 lists some PAH that are frequently found in ambient air. Those with vapor pressures above about 10x2013;8 kPa will be present in the ambient air substantially distributed between the gas and particulate phases. This test method will permit the collection of both phases. However, particulate-phase PAH will tend to be lost from the particulate filter during sampling due to desorption and volatilization.TABLE 1 Formulae and Physical Properties of Selective PAH Compound (Common Name) Formula Molecular Weight Melting Point, x00b0;C Boiling Point,A x00b0;C Vapor Pressure, kPa at 25x00b0;C Naphthalene C10H8 128.18 80.2
信息：ICS：13.040.20 (Ambient atmospheres) CCS：Z15 发布：2013 实施：

BS EN 16274-2021 过敏原分析方法。气相色谱-质谱法定量分析注射用香料中57种疑似过敏原
简介：
信息：ICS：71.100.60 CCS：B15/19 发布：2021-05-11 实施：2021-05-11

NF T75-631-2014 化妆品.分析方法.亚硝胺:使用液相色谱-质谱串联(HPLC-MS-MS)检测和测定化妆品中的N-亚硝基二乙醇胺(NDELA)
简介：La présente Norme internationale décrit une méthode de recherche et de quantification de la N-nitrosodiethanolamine (NDELA) dans les cosmétiques et les matières premières utilisées dans les cosmétiques.
信息：ICS：71.100.70 CCS：Y42 发布：2014-12-26 实施：2014-12-26

NY/T 2215-2012 含脂辐照食品鉴定.气相色谱质谱分析.2-烷基环丁酮法
简介：本标准规定了含脂类辐照食品的鉴定方法和判定依据。本标准适用于脂肪含量大于1%的食品。
信息：ICS：67.050 CCS：X04 发布：2012-12-07 实施：2013-03-01

ASTM D6209-21 环境空气中气态和颗粒多环芳烃测定的标准试验方法（用气相色谱/质谱分析在吸附剂支持的过滤器上收集）
简介：
信息：ICS：13.040.20 CCS：发布：2021-03-01 实施：

BS ISO 15819-2014 化妆品.分析方法.亚硝胺.使用液相色谱-质谱串联(HPLC-MS-MS)检测和测定化妆品中的N-亚硝基二乙醇胺(NDELA)
简介：
信息：ICS：71.100.70 CCS：Y42 发布：2014-11-30 实施：2014-11-30

ASTM D6209-98(2012) 环境空气中气态和颗粒状多环芳烃的测定标准试验方法（采用气相色谱/质谱分析的吸附剂背景滤光片收集）
简介：
信息：ICS：13.040.20 CCS：发布：2012-11-01 实施：

DIN ISO 16000-39-2020 室内空气. 第39部分: 胺的测定. 通过结合(超)高效液相色谱与高分辨率或串联质谱来对胺进行分析(ISO 16000-39-2019)
简介：ISO 16000 Part 39 - in combination with ISO 16000 Part 38 - specifies the measurement method for determining the mass concentration of primary, secondary and tertiary aliphatic and aromatic amines in indoor air using accumulated sampling and high-performance liquid chromatography
信息：ICS：13.040.20 CCS：发布：2020-12-01 实施：

KS H ISO 22634-2012 香烟.香烟主流烟气中苯并[a]芘的测定.气相色谱分析/质谱分析法
简介：이 표준은 궐련 주류연의 총 입자상 물질 내에 존재하는 벤조알파피렌(benzo[a]pyre
信息：ICS：65.160 CCS：X85 发布：2012-09-19 实施：2012-09-19

ASTM D8310-20 用多重反应监测液相色谱/质谱法（LC/MS/MS）分析土壤中目标酚（TPs）的标准试验方法
简介：
信息：ICS：13.080.10 CCS：发布：2020-02-01 实施：

ISO 15819-2014 化妆品.分析方法.亚硝胺:使用液相色谱-质谱串联(HPLC-MS-MS)检测和测定化妆品中的N-亚硝基二乙醇胺(NDELA)
简介：
信息：ICS：71.100.70 CCS：Y42 发布：2014-10 实施：

ASTM D7649-19 通过喷射脉冲注入和气相色谱/质谱分析测定氢燃料中痕量二氧化碳氩气氮气氧气和水的标准测试方法
简介：
信息：ICS： CCS：发布：2019-12-01 实施：

EN 16521-2014 化妆品.分析法.用气相色谱/质谱法鉴定及化验准备分析注射的化妆品样品中的12邻苯二甲酸盐
简介：This European Standard describes a GC/MS method for the assay of 12 phthalates, amongst which the 8 phthalates regulated by the European cosmetic regulation 1223/2009 [16]. This method is given for the analysis of samples ready for analytical injection from cosmetic products or raw materials used in cosmetic products. Samples should be compatible with GC analysis possibly after dilution. This method does not include requirements for the preparation of samples in cosmetic matrices for which direct injection in GC is not feasible.
信息：ICS：71.100.70 CCS：Y43 发布：2014-05 实施：

DIN ISO 22634-2012 香烟.香烟主流烟气中苯并[a]芘的测定.气相色谱分析/质谱分析法(ISO 22634-2008)
简介：
信息：ICS：65.160 CCS：X85 发布：2012-01 实施：

ISO/TS 11251-2019 纳米技术使用进化气体分析/气相色谱 - 质谱法对单壁碳纳米管样品中挥发性组分的表征
简介：
信息：ICS： CCS：发布：2019-09-25 实施：

SN/T 2297.5-2014 进出口石膏及石膏制品分析方法第5部分:硫含量的测定气相色谱-质谱法
简介：SN/T 2297的本部分规定了建筑用石膏及石膏制品中疏含量的气相色谱-质谱检测方法。本部分适用于建筑用石膏及石膏制品中单质硫含量的测定。
信息：ICS： CCS：Q62;Q27 发布：2014-04-09 实施：2014-11-01

ASTM E2866-2012 用液相色谱法/串联质谱法和加压流体萃取法分析土壤中二异丙基甲基磷酸酯,乙基膦酸,异丙基甲基膦酸,甲基膦酸和频哪基甲基膦酸的测定用标准试验方法
简介：This is a performance based method, and modifications are allowed to improve performance. Due to the rapid development of newer instrumentation and column chemistries, changes to the analysis described in this standard are allowed as long as better or equivalent performance data result. Any modifications shall be documented and performance data generated. The user of the data generated by this Standard shall be made aware of these changes and given the performance data demonstrating better or equivalent performance. Organophosphate pesticides affect the nervous system by disrupting the enzyme that regulates acetylcholine, a neurotransmitter. They were developed during the early 19th century, but their effects on insects, which were similar to their effects on humans, were discovered in 1932. Some are poisonous and were used as chemical weapon agents. Organophosphate pesticides are usually not persistent in the environment. , This test method is for the analysis of selected organophosphorous based pesticide degradation products. This method has been investigated for use with various soils. 1.1 This procedure covers the determination of Diisopropyl Methylphosphonate (DIMP), Ethyl Methylphosphonic Acid (EMPA), Isopropyl Methylphosphonic Acid (IMPA), Methylphosphonic Acid (MPA) and Pinacolyl Methylphosphonic Acid (PMPA), referred to collectively as organophosphonates (OPs) in this test method, in soil. This method is based upon solvent extraction of a soil by pressurized fluid extraction (PFE). The extract is filtered and analyzed by liquid chromatography/tandem mass spectrometry (LC/MS/MS). OPs are qualitatively and quantitatively determined by this method. 1.2 Units8212;The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.3 The Method Detection Limit (MDL), electrospray ionization (ESI) mode and Reporting Range for the OPs are listed in Table 1. 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. TABLE 1 Method Detection Limit and Reporting Range AnalyteESI ModeMDL (PPB)Reporting Range (PPB) Diisopropyl methylphosphonatePositive2.740-2000 Ethyl methylphosphonic acidNegative2.340-2000 Ethyl methylphosphonic acidPositive1.340-2000 Isopropyl methylphosphonic acidNegative5.740-2000 Isopropyl methylphosphonic acidPositive2.840-2000 Methylphosphonic acidPos......
信息：ICS：13.080.10 (Chemical characteristics of soil) CCS：Z18 发布：2012 实施：

DB34/T 3368.3-2019 印制电路板中有害物质分析方法第 3 部分：多溴联苯及多溴二苯醚的测定气相色谱-质谱法
简介：本部分规定了印制电路板中多溴联苯及多溴二苯醚的气相色谱-质谱法的原理、试剂、仪器工具、样品制备、分析步骤、结果计算、精密度和报告。本部分适用于印制电路板中多溴联苯及多溴二苯醚的测定。多溴联苯及多溴二苯醚的方法检出限为 6 mg/kg。
信息：ICS：31.18 CCS：L 30 发布：2019-07-01 实施：2019-09-01

DIN 38407-37-2013 德国检验水、废水和污泥的标准方法.联合可测物质(F组).第37部分:水中有机氯杀虫剂、多氯联苯和氯苯的测定.利用液液萃取后气相色谱和质谱检测的分析方法(GC-MS)(F 37)
简介：
信息：ICS：13.060.50 CCS：Z13;Z16 发布：2013-11 实施：

ASTM E2866-2012(2016) 采用液相色谱法/串联质谱法 (LC/MS/MS) 和加压流体萃取法分析土壤中二异丙基甲基磷酸酯, 乙基甲基膦酸, 异丙基甲基膦酸, 甲基膦酸和吡呐基甲基膦酸的测定用标准试验方法
简介：5.1x00a0;This is a performance based method, and modifications are allowed to improve performance. 5.1.1x00a0;Due to the rapid development of newer instrumentation and column chemistries, changes to the analysis described in this standard are allowed as long as better or equivalent performance data result. Any modifications shall be documented and performance data generated. The user of the data generated by this Standard shall be made aware of these changes and given the performance data demonstrating better or equivalent performance. 5.2x00a0;Organophosphate pesticides affect the nervous system by disrupting the enzyme that regulates acetylcholine, a neurotransmitter. They were developed during the early 19th century, but their effects on insects, which were similar to their effects on humans, were discovered in 1932. Some are poisonous and were used as chemical weapon agents. Organophosphate pesticides are usually not persistent in the environment.7,8 5.3x00a0;This test method is for the analysis of selected organophosphorous based pesticide degradation products. 5.4x00a0;This method has been investigated for use with various soils. 1.1x00a0;This procedure covers the determination of Diisopropyl Methylphosphonate (DIMP), Ethyl Methylphosphonic Acid (EMPA), Isopropyl Methylphosphonic Acid (IMPA), Methylphosphonic Acid (MPA) and Pinacolyl Methylphosphonic Acid (PMPA), referred to collectively as organophosphonates (OPs) in this test method, in soil. This method is based upon solvent extraction of a soil by pressurized fluid extraction (PFE). The extract is filtered and analyzed by liquid chromatography/tandem mass spectrometry (LC/MS/MS). OPs are qualitatively and quantitatively determined by this method. 1.2x00a0;Unitsx2014;The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.3x00a0;The Method Detection Limit2 (MDL), electrospray ionization (ESI) mode and Reporting Range3 for the OPs are listed in Table 1. 1.4x00a0;This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
信息：ICS：13.080.10 CCS：发布：2012 实施：

ISO 16000-39-2019 室内空气.第39部分:胺的测定.用（超）高效液相色谱结合高分辨率或串联质谱法分析胺
简介：
信息：ICS：13.040.20 CCS：发布：2019-05-31 实施：

DIN EN 16343-2013 化妆品.化妆品分析.化妆品制剂中3-碘-2-丙炔基正丁氨基甲酸酯(IPBC)的测定.液相色谱-质谱联用(LC-MS)法.德文版本EN 16343-2013
简介：
信息：ICS：71.100.70 CCS：Y42 发布：2013-08 实施：

BS DD ISO/TS 11251-2010 纳米技术.使用改进的气相分析/气相色谱-质谱分析仪在单壁碳纳米管样品中挥发性成分的特征
简介：
信息：ICS：07.030 CCS：A42 发布：2010-12-31 实施：2010-12-31

ASTM D7858-13(2018) 通过压力流体萃取测定土壤污泥和生物固体中双酚A的标准测试方法并通过液相色谱/串联质谱法分析
简介：
信息：ICS：13.080.10 CCS：发布：2018-09-01 实施：

NF M07-148-2013 石油产品 - 填充油中苯并芘 (BaP) 和选定的多环芳香烃 (PAH)含量的测定 - 使用双液相 (LC) 清洗和气相色谱/质谱 (GC/MS) 分析规程
简介：
信息：ICS：75.100 CCS：E30 发布：2013-07-19 实施：2013-07-19

ASTM E2881-18 用气相色谱 - 质谱法分析火焰碎片和液体样品中植物油脂的提取和衍生的标准试验方法
简介：
信息：ICS：67.200.10 CCS：发布：2018-06-01 实施：

NF T75-633-2013 化妆品 - 化妆品分析 - 化妆品制备过程中采用液相色谱-质谱联用法进行碘丙炔正丁胺甲酸酯 (IPBC) 的测定
简介：
信息：ICS：71.100.70 CCS：Y42 发布：2013-06-22 实施：2013-06-22

ISO/TS 11251-2010 纳米技术.使用改进的气相分析/气相色谱-质谱分析仪在单壁碳纳米管样品中挥发性成分的特征
简介：This Technical Specification specifies a method for the characterization of volatile components in single-wall carbon nanotubes (SWCNTs) samples using evolved gas analysis/gas chromatograph mass spectrometry (EGA/GCMS).
信息：ICS：07.030 CCS：A43 发布：2010-12-01 实施：2010-12-01

DB34/T 2979.2-2017 塑料及其制品中有机污染物分析方法第 2 部分：甲酰胺的测定气相色谱-质谱法
简介：本部分规定了塑料及其制品中甲酰胺的气相色谱-质谱联用测定方法。本部分适用于塑料及其制品中甲酰胺的测定。
信息：ICS：83.080.01 CCS：G 31 发布：2017-11-15 实施：2017-12-15

ASTM E2881-13 用气相色谱 - 质谱法分析火焰碎片和液体样品中植物油脂的提取和衍生的标准试验方法
简介：
信息：ICS：67.200.10 CCS：发布：2013-06-01 实施：

ASTM D7649-10 通过喷射脉冲注入和气相色谱/质谱分析测定氢燃料中痕量二氧化碳氩气氮气氧气和水的标准测试方法
简介：
信息：ICS： CCS：发布：2010-12-01 实施：

DB34/T 2979.3-2017 塑料及其制品中有机污染物分析方法第 3 部分：三（2-氯乙基）磷酸酯的测定气相色谱-质谱法
简介：本部分规定了塑料及其制品中三（2-氯乙基）磷酸酯(TCEP)的气相色谱-质谱联用测定方法。本部分适用于塑料及其制品中三（2-氯乙基）磷酸酯(TCEP)的测定。
信息：ICS：83.080.01 CCS：G 31 发布：2017-11-15 实施：2017-12-15

ASTM E2881-13e1 用气相色谱 - 质谱法分析火焰碎片和液体样品中植物油脂的提取和衍生的标准试验方法
简介：
信息：ICS：67.200.10 CCS：发布：2013-06-01 实施：

ISO/TS 11251:2010 纳米技术——单壁碳纳米管样品中挥发性成分的演化气体分析/气相色谱-质谱表征
简介：
信息：ICS： CCS：发布：2010-11-22 实施：

DB34/T 2979.1-2017 塑料及其制品中有机污染物分析方法第 1 部分：对特辛基苯酚的测定气相色谱-质谱法
简介：本部分规定了塑料及其制品中对特辛基苯酚的气相色谱-质谱联用测定方法。本部分适用于塑料及其制品中对特辛基苯酚的测定。
信息：ICS：83.080.01 CCS：G 31 发布：2017-11-15 实施：2017-12-15

DIN 10785-2013 咖啡和咖啡制品的分析.丙烯酰胺的测定.衍生化后高效液相色谱-质谱联用仪/质谱仪(HPLC-MS/MS)和气相色谱-质谱联用仪(GC-MS)
简介：
信息：ICS：67.140.20 CCS：X50 发布：2013-06 实施：

BS ISO 16000-14-2009 室内空气.总(气相和颗粒相)多氯联苯(PCBs)和多氯二苯并二恶英/多氯二苯并呋喃(PCDDs/PCDFs)含量的测定.使用高分辨率气相色谱法和质谱法进行提取,净化和分析
简介：
信息：ICS：13.040.20 CCS：Z15 发布：2009-06-30 实施：2009-06-30

ASTM D7649-10(2017) 通过喷射脉冲注入和气相色谱/质谱分析测定氢燃料中痕量二氧化碳氩气氮气氧气和水的标准测试方法
简介：
信息：ICS： CCS：发布：2017-04-01 实施：

BS EN 16343-2013 化妆品. 化妆品分析. 化妆品制备过程中采用液相色谱-质谱联用法进行碘丙炔正丁胺甲酸酯 (IPBC) 的测定
简介：
信息：ICS：71.100.70 CCS：Y43 发布：2013-05-31 实施：2013-05-31

ISO 16000-14:2009 室内空气.第14部分:总（气相和颗粒相）多氯二恶英类联苯（PCBs）和多氯联苯对二恶英/二苯并呋喃（PCDDs/PCDFs）的测定.高分辨率气相色谱法和质谱法萃取、净化和分析
简介：
信息：ICS：13.040.20 CCS：发布：2009-05-15 实施：

ASTM C1845-16 使用高压离子色谱（HPIC）通过电感耦合等离子体质谱法（ICP-MS）同位素分析从铀原子分离镧系元素的标准实践
简介：
信息：ICS：27.120.30 CCS：发布：2016-06-01 实施：

EN 16343-2013 化妆品.化妆品分析.化妆品备制中碘代丙炔基正丁氨基甲酸酯(IPBC)的测定.液相色谱-质谱联用(LC-MS)法
简介：This European Standard specifies a method for the quantitative determination of 3-iodo-2-propynyl butylcarbamate (IPBC) in the concentration range from 0,005 g/100 g to 0,1 g/100 g - Annex V No. 56 in Regulation (EC) No 1223/2009 on cosmetic products.
信息：ICS：71.100.70 CCS：Y42 发布：2013-05-01 实施：2013-05-01

ISO 16000-14-2009 室内空气.第14部分:总(气体和颗粒相)二噁英类多氯联苯(PCBs)和多氯代二苯并-对-二噁英/二苯并呋喃(PCDDs/PCDFs)的测定.提取,净化和采用高分辨率气相色谱和质谱分析
简介：
信息：ICS：13.040.20 CCS：C51 发布：2009-05 实施：

ASTM E2997-16 通过气相色谱 - 质谱分析生物柴油产品的标准测试方法
简介：
信息：ICS： CCS：发布：2016-03-01 实施：

ASTM D6209-13 环境空气中气态和颗粒状多环芳烃的测定标准试验方法（采用气相色谱/质谱分析的吸附剂背景滤光片收集）
简介：
信息：ICS：13.040.20 CCS：发布：2013-04-01 实施：

ASTM D7597-2009 用液相色谱法/串联质谱分析水中二异丙基甲基磷酸酯、乙基氢氨基磷酸盐、乙基膦酸、异丙基甲基膦酸、甲基膦酸和频哪基甲基膦酸的测定用标准试验方法
简介：Organophosphate pesticides affect the nervous system by disrupting the enzyme that regulates acetylcholine, a neurotransmitter. They were developed during the early 19th century, but their effects on insects, which are similar to their effects on humans, were discovered in 1932. Some are poisonous and were used as chemical weapon agents. Organophosphate pesticides are usually not persistent in the environment. , This test method is for the analysis of selected organophosphorous-based chemical weapon agent degradation products from Sarin (GB), Soman (GD), Tabun (GA) and VX. This method has been investigated for use with reagent and surface water.1.1 This procedure covers the determination of diisopropyl methylphosphonate (DIMP), ethyl hydrogen dimethylamidophosphate (EHDMAP), ethyl methylphosphonic acid (EMPA), isopropyl methylphosphonic acid (IMPA), methylphosphonic acid (MPA) and pinacolyl methylphosphonic acid (PMPA) (referred to collectively as organophosphonates in this test method) in surface water by direct injection using liquid chromatography (LC) and detected with tandem mass spectrometry (MS/MS) using electrospray ionization (ESI). These analytes are qualitatively and quantitatively determined by this method. This method adheres to single reaction monitoring (SRM) mass spectrometry. 1.2 This test method has been developed in support of the National Homeland Security Research Center, US EPA by Region 5 Chicago Regional Laboratory. 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 The detection verification level (DVL) and reporting range for the organophosphonates are listed in Table 1. 1.4.1 The DVL is required to be at a concentration at least three times below the reporting limit (RL) and have a signal/noise ratio greater than 3:1. Fig. 1 displays the signal/noise ratios at the DVLs for the organophosphonates in the ESI positive mode and Fig. 2 in the ESI negative mode. 1.4.2 The reporting limit is the concentration of the Level 1 calibration standard as shown in Table 2 for the organophosphonates except for MPA in the ESI negative mode which is at Level 2 due to not meeting the DVL criteria at the lower concentration level. The DVL for MPA in the ESI negative mode is at 20 x03BC;g/L, which forces a raised reporting limit. However, the multi-laboratory validation required a spike of all target analytes at Level 1 concentrations. The mean recovery for MPA in the ESI negative mode at this level was 98.7 % as shown in Table 3. If your instrumentx2019;s sensitivity can meet the requirements in this test method, MPA may have a 50 x03BC;g/L reporting limit. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
信息：ICS：13.060.50 (Examination of water for chemical subst CCS：C51 发布：2009-01-01 实施：

ASTM E2997-2016 采用气象色谱-质谱法分析生物柴油产品的标准试验方法
简介：4.1x00a0;This test method specifically identifies fatty acid methyl esters and petroleum distillates found in biodiesel products. Derivatization is not necessary to identify FAMEs. 4.1.1x00a0;This test method is useful when biodiesel products are suspected as a fuel source in a fire or a fuel product case and the identification of the x201c;biox201d; portion of the fuel is of interest. 4.1.2x00a0;The identification of biodiesel in samples from a fire scene can support the field investigatorx2019;s opinion regarding the origin and cause of the fire or provide investigative leads. 4.1.3x00a0;The identification of biodiesel in a sample of fuel from a dispensing container or fuel tank can support the field investigatorx2019;s findings in a fuel product tampering investigation. 4.2x00a0;FAMEs can be identified in debris samples using headspace extraction techniques and GC-MS. 4.2.1x00a0;Solvent extraction may be required to further identify and characterize the FAME content in biodiesel. 4.2.2x00a0;The presence of FAMEs and petroleum diesel is a strong indication of a biodiesel product, as FAMEs are not naturally occurring. 4.3x00a0;Biodiesel products can be identified in liquid samples by GC-MS after appropriate solvent dilution or extraction. 4.4x00a0;Biodiesel is available in different blends, where B100 is 100 % biodiesel (typically 100 % transesterified vegetable oils or recycled restaurant greases) and B2 is 2 % biodiesel and 98 % petroleum diesel, with variations in between. 4.5x00a0;This test method is a sensitive technique and can detect quantities as small as 7 x03bc;L of biodiesel residue in an extract from a debris sample. 4.6x00a0;This test method can be hampered by coincident extraction of interfering compounds present in the debris samples. 4.7x00a0;Depending on the extraction method used, this could be a destructive technique and whenever possible the entire sample should not be used for the procedure. Solvent extracted portions of the sample are not suitable for resampling. 4.8x00a0;Alternate methods of extraction or analysis exist and may be suitable for use in obtaining similar results and conclusions. 1.1x00a0;This test method covers the analysis and identification of the fatty acid methyl esters (FAMEs) and petroleum distillate components of biodiesel products. 1.2x00a0;This test method is suitable for identifying the components of biodiesel products in extracts of debris samples or in liquid samples.
信息：ICS： CCS：发布：2016 实施：

ASTM D7858-13 通过压力流体萃取测定土壤污泥和生物固体中双酚A的标准测试方法并通过液相色谱/串联质谱法分析
简介：
信息：ICS：13.080.10 CCS：发布：2013-04-01 实施：

ASTM D7597-2009e1 用液相色谱法/串联质谱分析水中二异丙基甲基磷酸酯、乙基氢氨基磷酸盐、乙基膦酸、异丙基甲基膦酸、甲基膦酸和吡呐基甲基膦酸的测定用标准试验方法
简介：Organophosphate pesticides affect the nervous system by disrupting the enzyme that regulates acetylcholine, a neurotransmitter. They were developed during the early 19th century, but their effects on insects, which are similar to their effects on humans, were discovered in 1932. Some are poisonous and were used as chemical weapon agents. Organophosphate pesticides are usually not persistent in the environment. , This test method is for the analysis of selected organophosphorous-based chemical weapon agent degradation products from Sarin (GB), Soman (GD), Tabun (GA) and VX. This method has been investigated for use with reagent and surface water.1.1 This procedure covers the determination of diisopropyl methylphosphonate (DIMP), ethyl hydrogen dimethylamidophosphate (EHDMAP), ethyl methylphosphonic acid (EMPA), isopropyl methylphosphonic acid (IMPA), methylphosphonic acid (MPA) and pinacolyl methylphosphonic acid (PMPA) (referred to collectively as organophosphonates in this test method) in surface water by direct injection using liquid chromatography (LC) and detected with tandem mass spectrometry (MS/MS) using electrospray ionization (ESI). These analytes are qualitatively and quantitatively determined by this method. This method adheres to single reaction monitoring (SRM) mass spectrometry. 1.2 This test method has been developed by US EPA Region 5 Chicago Regional Laboratory (CRL). 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 The detection verification level (DVL) and reporting range for the organophosphonates are listed in Table 1. 1.4.1 The DVL is required to be at a concentration at least three times below the reporting limit (RL) and have a signal/noise ratio greater than 3:1. Fig. 1 displays the signal/noise ratios at the DVLs for the organophosphonates in the ESI positive mode and Fig. 2 in the ESI negative mode. 1.4.2 The reporting limit is the concentration of the Level 1 calibration standard as shown in Table 2 for the organophosphonates except for MPA in the ESI negative mode which is at Level 2 due to not meeting the DVL criteria at the lower concentration level. The DVL for MPA in the ESI negative mode is at 20 x03BC;g/L, which forces a raised reporting limit. However, the multi-laboratory validation required a spike of all target analytes at Level 1 concentrations. The mean recovery for MPA in the ESI negative mode at this level was 98.7 % as shown in Table 3. If your instrumentx2019;s sensitivity can meet the requirements in this test method, MPA may have a 50 x03BC;g/L reporting limit. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. TABLE 1 Detection Verification Level and Reporting Range AnalyteESI ModeDVL (x03BC;g/L)Reporting Range (x03BC;g/L) Diisopropyl methylphosphonatePositive15x2013;150 Ethyl hydrogen dimethylamidophosphateNegative0.255
信息：ICS：13.060.50 CCS：Z16 发布：2009-01-01 实施：